Dr. Prinson P Samuel
Assistant Professor & Research Guide
M.Sc. M.Tech. Ph.D (Germany), PDF (Germany)
Personal Website
Bio
Prinson P. Samuel is an Indian Chemistry educator and researcher. He completed his M.Sc. in Chemistry from University of Kerala and M. Tech. in Industrial Catalysis from Cochin University of Science and Technology. Shortly, he joined National Chemical Laboratory, Pune in the research group of Dr. A. P. Singh (Senior scientist) and worked towards developing an industrial catalytic technology for bisphenol A synthesis in a collaborative project with GE India Ltd. After being awarded the International Research and Training Group (IRTG) fellowship funded by German Research Foundation (DFG), he joined the group of Prof. Dr. Carola Schulzke in the University of Göttingen to pursue his doctoral studies in the biomimetic chemistry of Mo and W. In 2011, he was awarded a Doctorate degree from the University of Göttingen. Later on, he joined the research group of world renouned chemist Prof. Dr. Herbert W. Roesky at University of Goettingen, for his postdoctoral research and actively involved in exploring the chemistry of low coordinate transition metals and main group elements for more than six years. Currently he an assitant professor of Chemistry at Christian College Chengannur. He has co-authored more than 50 research articles with an h-index of above 25. He is an author of the book "Molybdenum and Tungsten Cofactor Model Chemistry" published by Nova Sci. Publ. New York.
Contact
prinsonpsamuel@christiancollege.ac.in
9605586290
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M.Sc. Chemistry
University of Kerala St. Stephens College, Pathanapuram |
May 2003 |
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M.Tech. Industrial Catalysis
CUSAT Department of Applied Chemistry |
May 2006 |
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Ph.D. Chemistry
University of Goettingen, Germany Faculty of Chemistry |
Jan 2011 |
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Post Doctoral
University of Goettingen Germany Faculty of Chemistry |
Feb 2011- May 2017 |
1) K. U. Nair, P. P. Samuel "Theoretical insights into oxyisocyclointegrin: DFT, binding affinity, and pharmacokinetic evaluation for protein kinase inhibition" J. Chem. Sci. 138 (2026) 47.
2) R. Unni, R. Reshmy, R. Varghese, Y. B. Dalvi, R. Augustine, T. J. Mathew, A. Abraham, P. P. Samuel “3D-pored Ixora Coccinea Linn. Extracted nanocellulose-curcumin composites for tissue engineering applications” Int. J. Biol. Macromolecules (2025) 147727.
3) P. P. Samuel, S. Kundu, C. Mohapatra, A. George, S. De, P. Parameswaran, H. W. Roesky "One Pot Catalytic Synthesis of Geminal- Diazide and the Direct Conversion to Safe Materials" Eur. J. Org. Chem. 2017, 2327.
4) A. C. Ghosh, P. P. Samuel, C. Schulzke "Synthesis, characterization and oxygen atom transfer reactivity of a pair of Mo(IV)O- and Mo(VI)O2-enedithiolate complexes – a look at both ends of the catalytic transformation" Dalton Trans. 46 (2017) 7523.
5) M. Damjanovic, P. P. Samuel, H.W. Roesky, M. Enders "NMR Analysis of an Fe(I)-Carbene Complex with Strong Magnetic Anisotropy" Dalton Trans. 46 (2017) 5159.
6) S. Kundu, P. P. Samuel, S. Sinhababu, A. V. Luebben,B. Dittrich, D. M. Andrada, G. Frenking, A. C. Stückl, B. Schwederski, A. Paretzki, W. Kaim, H. W. Roesky "Organosilicon Radicals with Si–H and Si–Me Bonds from Commodity Precursors" J. Am. Chem. Soc., 139 (2017), 11028.
7) S. Kundu, C. Mohapatra, P. P. Samuel, J. Kretsch, M. G. Walawalkar, R. Herbst-Irmer, D. Stalke, Sriman De, D. Koley, H. W. Roesky "An unprecedented 1,4-diphospha-2,3-disila butadiene (–P=Si–Si=P–) derivative and a 1,3-diphospha-2-silaallyl anion, each stabilized by the amidinate ligand" Chem. Commun., 53 (2017) 192.
8) S. Kundu, P. P. Samuel, A. Luebben, D. M. Andrada, G. Frenking, B. Dittrich, H. W. Roesky "Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents" Dalton Trans., 46 (2017) 7947
9) C. Mohapatra, P. P. Samuel, B. Li, B. Niepötter, C. J. Schurmann, R. H.-Irmer, D. Stalke, B. Maity, D. Koley, H. W. Roesky "Insertion of Cyclic Alkyl(amino) Carbene into the Si-H Bonds of Hydrochlorosilanes" Inorg. Chem. 55 (2016) 1953.
10) P. P. Samuel, R. Neufeld, K. C. Mondal, H. W. Roesky, R. H.-Irmer, D. Stalke, S. Demeshko, F. Meyer, V. C. Rojisha, S. De, P. Parameswaran, A. C. Stuckl, W. Kaim, J. H. Christian, J. K. Bindra N. S. Dalal "Cr(I)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes" Chem. Sci. 6 (2015) 3148.
11) S. P. Sarish,† P. P. Samuel,† H. W. Roesky, C. Schulzke, K. Nijesh, S. De, P. Parameswaran "Multiple Cycloadditions of Reactions of Ketones with a β-diketiminate Al compound" Chem. Eur. J. 21 (2015) 19041 (†equal contribution)
12) C. Mohapatra, K. C. Mondal, P. P. Samuel, H. Keil, B. Niepötter, R. H.-Irmer, D. Stalke, S. Dutta, D. Koley H. W. Roesky "A Stable Dimer of SiS2 Arranged between Two Carbene Molecules" Chem. Eur. J. 21 (2015) 12572.
13) B. Dittrich, C. M. Wandtke, A. Meents, K. Pröpper, K. C. Mondal, P. P. Samuel, N. A. SK, A. P. Singh, H. W. Roesky, N. Sidhu "Aspherical-Atom Modeling of Coordination Compounds by Single-Crystal X-ray Diffraction Allows the Correct Metal Atom To Be Identified" ChemPhysChem 16 (2015) 412.
14) K. Samedov, R. West, P. W. Percival, Jean-C. Brodovitch, L. Chandrasena, M. Mozafari, R. Tacke, K. Junold, C. Kobelt, P. P. Samuel, R. Azhakar, K. C. Mondal, H. W. Roesky, M. Driess, W. Wang “Free Radicals of N-Donor-Stabilized Silicon (II) Compounds Probed by Muon Spin Spectroscopy” Organometallics 34 (2015) 3532.
15) P. P. Samuel, K. C. Mondal, N. A. Sk, H. W. Roesky, E. Carl, R. Neufeld, D. Stalke, S. Demeshko, F. Meyer, L. Ungur, L. F. Chibotaru, J. Christian, V. Ramachandran, J. van Tol, N. S. Dalal "Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(I) Complexes" J. Am. Chem. Soc. 136 (2014) 11964.
16) P. P. Samuel, Y. Li , H. W. Roesky, V. Chevelkov , A. Lange, A. Burkhardt, B. Dittrich "Synthetic Access to a Hydrocarbon-Soluble Trifluorinated Ge(II) Compound and its Sn(II) Congener" J. Am. Chem. Soc. 136 (2014) 1292.
17) K. C. Mondal, P. P. Samuel, H. W. Roesky, E. Carl, R. H.-Irmer, D. Stalke, B. Schwederski, W. Kaim, L. Ungur, L. F. Chibotaru, M. Hermann, G. Frenking "Stabilization of a Cobalt-Cobalt Bond by Two Cyclic Alkyl Amino Carbenes" J. Am. Chem. Soc. 136 (2014) 1770.
18) K. C. Mondal, P. P. Samuel, Y. Li, H. W. Roesky, S. Roy, L. Ackermann, N. S. Sidhu, G. M. Sheldrick, E. Carl, S. Demeshko, S. De, P. Parameswaran, L. Ungur, L. F. Chibotaru, D. M. Andrada "A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies" Eur. J. Inorg. Chem. 2014 (2014) 818.
19) K. C. Mondal, P. P. Samuel, H. W. Roesky, R. R. Aysin, L. A. Leites, S. Neudeck, J. Lübben, B. Dittrich, N. Holzmann, M. Hermann, G. Frenking "One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene" J. Am. Chem. Soc. 136 (2014) 8919.
20) Y. Li, K. C. Mondal, P. P. Samuel, H. Zhu, C. M. Orben, S. Panneerselvam, B. Dittrich, B. Schwederski, W. Kaim, T. Mondal, D. Koley, H. W. Roesky "C-4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication" Angew. Chem. Int. Ed. 53 (2014) 4168.
21) K. C. Mondal,† P. P. Samuel,† H. W Roesky, B. Niepötter, R. Herbst-Irmer, D. Stalke, F. Ehret, W. Kaim, B. Maity, D. Koley "Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane" Chem. Eur. J. 20 (2014) 9240. (†equal contribution)
22) B. Niepötter, R. H.-Irmer, D. Kratzert, P. P. Samuel, K. C. Mondal, H. W. Roesky, P. Jerabek, G. Frenking, D. Stalke “Experimental Charge Density Study of a Silylone" Angew. Chem. Int. Ed. 53 (2014) 2766.
23) B. Niepötter, R. H.-Irmer, D. Kratzert, P. P. Samuel, K. C. Mondal, H. W. Roesky, P. Jerabek, G. Frenking, D. Stalke “Experimentelle Elektronendichteuntersuchung eines Silylons" Angew. Chem. 126 (2014) 2806.
24) A. Mukherjee, P. P. Samuel, C. Schulzke, S. Mondal "Main group chemistry of 9-hydroxophenalenone: Syntheses and structural characterization of the alkaline earth and zinc complexes" J. Chem. Sci. 126 (2014) 1581.
25) P. P. Samuel, K. C. Mondal, H. W. Roesky, M. Hermann, G. Frenking, S. Demeshko, F. Meyer, A. C. Stückl, J. H. Christian, N. S. Dalal, L. Ungur, L. F. Chibotaru, K. Pröpper, A. Meents, B. Dittrich "Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature" Angew. Chem. Int. Ed. 52 (2013) 11817.
26) A. P. Singh , P. P. Samuel, H. W. Roesky, M. C. Schwarzer, G. Frenking, N. S. Sidhu, B. Dittrich "A Singlet Biradicaloid Zinc Compound and Its Nonradical Counterpart" J. Am. Chem. Soc. 135 ( 2013) 7324.
27) P. P. Samuel, A. P. Singh, S. P. Sarish, J. Matussek, I. Objartel, H. W. Roesky, D. Stalke "Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine" Inorg. Chem. 52 (2013) 1544.
28) K. C. Mondal, P. P. Samuel, M.Tretiakov, A. P. Singh, H. W. Roesky, A. C. Stückl, B. Niepötter, E. Carl, H. Wolf, R. H.-Irmer, D. Stalke "Easy Access to Silicon(0) and Silicon(II) Compounds" Inorg. Chem. 52 (2013) 4736.
29) A. P. Singh, P. P. Samuel, K. C. Mondal, H. W. Roesky, N. S. Sidhu, B. Dittrich "Lewis Base Stabilized Group 14 Metalylenes" Organometallics 32 (2013) 354.
30) Y. Li, J. Wang, Y. Wu, H. Zhu, P. P. Samuel, H. W. Roesky "Synthesis of metallasiloxanes of group 13-15 and their application in catalysis" Dalton. Trans. 42 (2013) 13715.
31) M. Tretiakov, Y. G. Shermolovich, A. P. Singh, P. P. Samuel, H. W. Roesky, B. Niepötter, A. Visscher, D. Stalke "Lewis-base stabilized diiodine adducts with N-heterocyclic chalcogenamides" Dalton. Trans. 42 (2013) 12940.
32) A. Mukherjee, T. K. Sen, P. K. Ghorai, P. P. Samuel, C. Schulzke, S. K. Mandal "Phenalenyl-Based Organozinc Catalysts for Intramolecular Hydroamination Reactions: A Combined Catalytic, Kinetic, and Mechanistic Investigation of the Catalytic Cycle" Chem. Eur. J. 18 (2012) 10530.
33) P. P. Samuel, R. Azhakar, R. S. Ghadwal, S. S. Sen, H. W. Roesky, M. Granitzka, J. Matussek, R. H.-Irmer , D. Stalke "Stable Silaimines with Three- and Four-Coordinate Silicon Atoms" Inorg. Chem. 51 (2012) 11049.
34) S. Khan, P. P. Samuel, R. Michel, J. M. Dieterich, R. A. Mata, J.-P. Demers, A. Lange, H. W. Roesky, D. Stalke "Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand" Chem. Commun. 48 (2012) 4890.
35) B. Nekoueishahraki, P. P. Samuel, H. W. Roesky, D. Stern, J. Matussek, D. Stalke "Organobismuth(III) and Dibismuthine Complexes Bearing N,N '-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity" Organometallics 31 (2012) 6697.
36) S. S. Sen, S. Khan, P. P. Samuel, H. W. Roesky "Chemistry of functionalized silylenes" Chem. Sci. 3 (2012) 659.
37) P. P. Samuel, S. Horn, A. Döring, K. G. V. Havelius, S. Reschke, S. Leimkühler, M. Haumann, C. Schulzke "A crystallographic and Mo-K-edge XAS study of molybdenum oxo bis-, mono- and non-dithiolene complexes and DMSOR: evaluation of geometrical first coordination shell and electronic properties" Eur. J. Inorg. Chem. (2011) 4387.
38) S. P. Sarish, A. Jana, H. W. Roesky, P. P. Samuel, C. E. A. Andrade, B. Dittrich, C. Schulzke “Synthesis of a Lewis Base Stabilized Dimer of N-Substituted Hydrosila Hydrazone and a Silaaziridine" Organometallics 30 (2011) 912.
39) A. Jana, R. Azhakar, S. P. Sarish, P. P. Samuel, H. W. Roesky, C. Schulzke, D. Koley "Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline" Eur. J. Inorg. Chem. 32 (2011) 5006.
40) A. Jana, P. P. Samuel, G. Tavcar, H.W. Roesky, C. Schulzke "Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon" J. Am. Chem. Soc. 132 (2010) 10164.
41) A. Jana, P. P. Samuel, H.W. Roesky, C. Schulzke "Preparation of iron carbonylcomplexes of Ge(II) and Sn(II) each with a terminal fluorine atom" J. Flur. Chem. 131 (2010) 1096.
42) A. Jana, H.W. Roesky, C. Schulzke, P.P. Samuel "Reaction of Tin(II) Hydride with Compounds Containing Aromatic C−F Bonds" Organometallics 29 (2010) 4837.
43) A. Jana, H.W. Roesky, C. Schulzke, P. P. Samuel, A. Döring "Synthesis and Reaction of Monomeric Germanium(II) and Lead(II) Dimethylamide and the Synthesis of Germanium(II) Hydrazide by Clevage of one N−H bond of Hydrazine" Inorg. Chem. 49 (2010) 5554.
44) A. Jana, H. W. Roesky, C. Schulzke, P. P. Samuel "An Efficient Route for the Synthesis of a Tin(II) Substituted Carbodiimide from a Diazo Compound" Inorg. Chem. 49 (2010) 3461.
45) A. Jana, S. P. Sarish, H. W. Roesky, C. Schulzke, P. P. Samuel "A rational design for an efficient synthesis of a monomeric hydroxide" Chem. Commun. 46 (2010) 707.
46) N. D. Reddy, A. Jana, H. W. Roesky, P. P. Samuel, C. Schulzke "Synthesis of phosphine substituted β-diketiminate based isomeric Ge(II) complexes" Dalton Trans. 39 (2010) 234.
47) J. Li, C. Schulzke, S. Merkel, H. W. Roesky, P. P. Samuel, A. Döring, D. Stalke "Synthesis and Characterization of N-heterocyclic Carbene Complexes of Titanium (IV) and Titanium(III)" Z. Anorg. Allg. Chem. 636 (2010) 511.
48) A. Jana, H. W. Roesky, C. Schulzke, P. P. Samuel "Insertion Reaction of a Silylene into a N−H Bond of Hydrazine and a [1+4] Cycloaddition with Diphenyl Hydrazone" Organometallics 28 (2009) 6574.
49) S. Shylesh, M. P. Kapoor, L.R. Juneja, P. P. Samuel, C. Srilakshmi, A. P. Singh “Catalytic Meerwein-Ponndorf-Verley reductions over mesoporous silica supports: Rational design of hydrophobic mesoporous silica for enhanced stability of aluminum doped mesoporous catalysts” J. Mol. Catal. A: Chem. 301 (2009) 118.
50) S. Shylesh, P. P. Samuel, S. Sisodiya, A. P. Singh "Periodic mesoporous organosilicas: an overview towards catalysis" Catal. Surv. Asia. 12 (2008) 266.
51) P. P. Samuel, S. Shylesh, A.P. Singh "Catalytic properties of tin-containing mesoporous molecular sieves in the selective reduction of carbonyl compounds (Meerwein-Ponndorf-Verley (MPV) reaction" J. Mol. Catal. A. Chem. 266 (2007) 11.
52) S. Shylesh, P. P. Samuel, Ch. Srilakshmi, R. Parischa, A.P. Singh "Sulfonic acid functionalized mesoporous silicas and organosilicas: synthesis, characterization and catalytic applications" J. Mol. Catal. A. Chem. 274 (2007) 153.
53) S. Shylesh, P. P. Samuel, A.P. Singh "Cyclooctene epoxidation over mesoporous organo vanadosilicates having –CH2-CH2- groups in the frame wall positions" Catal. Commun. 8 (2007) 894.
54) S. Shylesh, P. P. Samuel, A.P. Singh "Synthesis of hydrothermally stable aluminium-containing ethane-silica hybrid mesoporous materials using different aluminium sources" Micropor. Mesopor. Mater. 100 (2007) 250.
55) S. Shylesh, P. P. Samuel, A.P. Singh "Chromium containing small pore mesoporous silicas: Synthesis, characterization and catalytic behavior in the liquid phase oxidation of cyclohexane" Appl. Catal. A. Gen. 318 (2007) 128.
56) A. P Singh, S. Shylesh, P. P. Samuel “Synthesis, Characterization and Catalytic Applications of Vanadium-containing Ethane-bridged Hybrid Periodic Mesoporous Organosilicas” Stud. Surf. Sci. Catal. 172 (2007) 357.
57) S. Shylesh, P. P. Samuel, R. Parischa, A. P. Singh “Ethane bridged hybrid mesoporous silsesquioxanes with sulfonic acid functionalities: synthesis, characterization and catalytic applications” Stud. Surf. Sci. Catal 170 (2007) 1899.
No Publication in Books/Seminars/Symposia added.
A. P Singh, S. Shylesh, P. P. Samuel “Synthesis, Characterization and Catalytic Applications of Vanadium-containing Ethane-bridged Hybrid Periodic Mesoporous Organosilicas” Stud. Surf. Sci. Catal. 172 (2007) 357.
S. Shylesh, P. P. Samuel, R. Parischa, A. P. Singh “Ethane bridged hybrid mesoporous silsesquioxanes with sulfonic acid functionalities: synthesis, characterization and catalytic applications” Stud. Surf. Sci. Catal 170 (2007) 1899.
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